MA Haixia, LI Laihao, YANG Xianqing, WU Yanyan, ZHOU Wanjun, DIAO Shiqiang, CHEN Shengjun. Spectrophotometric determination of formaldehyde in aquatic products[J]. South China Fisheries Science, 2008, 4(6): 26-32.
Citation: MA Haixia, LI Laihao, YANG Xianqing, WU Yanyan, ZHOU Wanjun, DIAO Shiqiang, CHEN Shengjun. Spectrophotometric determination of formaldehyde in aquatic products[J]. South China Fisheries Science, 2008, 4(6): 26-32.

Spectrophotometric determination of formaldehyde in aquatic products

More Information
  • Received Date: June 26, 2008
  • Revised Date: September 03, 2008
  • Formaldehyde in aquatic products was determined by acetyle acetone spectrophotometry in the present research. The colorimetric parameters and the preprocessing of samples in the method were studied, and the feasibility of using acetyle acetone spectrophotometry as a method in rapid determination of formaldehyde in aquatic products was discussed as well. Results showed that the optimal soaking time was 10 min during ice incubation, then soaking solution pH value was adjusted to 6 with 100 g · L-1 KOH solution, and the optimal colorimetric time was 3 min at a wave length of 412 nm. The linear relation between absorbency and formaldehyde dosage was very good (R2=0.9998) while the formaldehyde content varied within a range of 0~2.5 μg · mL-1. The recovery of the present method was 89.50%~94.25%, while the recovery of the distillation method was only 64.17%~76.92%. Comparing with the latter method, the recovery of present method was much better.RSD (%) of the present method was 2.93%, and the minimum detectability of formaldehyde in samples was 0.9 mg · kg-1.

  • [1]
    [2]
    中国标准出版社第一编辑室. 无公害食品标准汇编水产品卷[M]. 北京: 中国标准出版社, 2002.
    [3]
    范荻, 潘振球, 曹华娟, 等. 食品中甲醛测定前处理的干扰问题探讨[J]. 实用预防医学, 2002, 19(4): 412-413. doi: 10.3969/j.issn.1006-3110.2002.04.082
    [4]
    高鹤娟. 食品卫生检验方法"理化部分"注解[M]. 北京: 卫生部食品卫生监督检验所, 1987.
    [5]
    吴鑫德, 刘勋钢. 乙酰丙酮法测定甲醛反应的产物[J]. 分析化学, 2002, 30(12): 1 463-1 465. doi: 10.3321/j.issn:0253-3820.2002.12.014
    [6]
    塔娜, 师邱毅. 测定食品中甲醛含量时所用三种萃取剂比较[J]. 内蒙古预防医学, 1998, 23(3): 125-126. https://d.wanfangdata.com.cn/periodical/Ch9QZXJpb2RpY2FsQ0hJTmV3UzIwMjQxMTA1MTcxMzA0Eg5RSzE5OTgwMDg4MDQyMhoIN2kydnJ1OWc%3D
    [7]
    王树庆, 苏蕾. 食品中甲醛的含量与控制[J]. 食品工业科技, 2004, 25(11): 137-138. doi: 10.3969/j.issn.1002-0306.2004.11.045
    [8]
    李绮, 邢志强, 李莹, 等. 保鲜香菇中甲醛含量的分析研究[J]. 辽宁大学学报: 自然科学版, 2004, 31(2): 105-106. doi: 10.3969/j.issn.1000-5846.2004.02.003
    [9]
    马敬军, 周德庆, 张双灵. 水产品中甲醛本底含量与产生机理的研究进展[J]. 海洋水产研究, 2004, 25(4): 85-89. doi: 10.3969/j.issn.1000-7075.2004.04.015
  • Related Articles

    [1]MA Lisha, YIN Yi, TIAN Fei, XIE Wenping, SHAN Qi, ZHENG Guangming, LI Lichun, LIU Shugui, DAI Xiaoxin, ZHAO Cheng, WEI Linting, LIN Jiawei. Rapid determination of prometryn in aquatic products by QuEChERS combined with gas chromatography mass spectrometry[J]. South China Fisheries Science, 2022, 18(4): 170-176. DOI: 10.12131/20210351
    [2]ZHAO Donghao, WANG Xufeng, WANG Qiang, LI Zhiguang, HUANG Ke, LI Liudong. Influence of solvent on nitrofuran metabolites response by liquid chromatography-tandem mass spectrometry[J]. South China Fisheries Science, 2016, 12(6): 108-114. DOI: 10.3969/j.issn.2095-0780.2016.06.014
    [3]ZHAO Donghao, LI Zhiguang, WANG Xufeng, WANG Qiang, LI Yongxian, HUANG Ke, LI Liudong. Optimization of determination of nitrofuran metabolites in aquatic products by liquid chromatography tandem mass spectrometry[J]. South China Fisheries Science, 2015, 11(6): 58-64. DOI: 10.3969/j.issn.2095-0780.2015.06.008
    [4]WANG Xu, LI Na, GENG Anjing, YANG Hui, WANG Fuhua. Determination of five arsenic species in seafood using high performance liquid chromatography (HPLC) coupled with inductively coupled plasma mass spectrometry (ICP-MS)[J]. South China Fisheries Science, 2013, 9(2): 50-56. DOI: 10.3969/j.issn.2095-0780.2013.02.009
    [5]SUN Xiumei, MEI Guangming, CHEN Xuechan, GUO Yuanming, CHEN Peng. Determination of 15 polycyclic aromatic hydrocarbons in aquatic products by HPLC-Fluorescence[J]. South China Fisheries Science, 2012, 8(3): 48-53. DOI: 10.3969/j.issn.2095-0780.2012.03.007
    [6]WU Yanyan, LIU Fajia, LI Laihao, YANG Xianqing, ZHOU Wanjun, DENG Jianchao. Determination of nitrite in salted fish by improved ion chromatography[J]. South China Fisheries Science, 2011, 7(6): 1-6. DOI: 10.3969/j.issn.2095-0780.2011.06.001
    [7]ZHAO Yongqiang, YANG Xianqing, QI Bo, LI Laihao, DIAO Shiqiang, CHEN Shengjun. Determination of sulfate group in agar by ion chromatography[J]. South China Fisheries Science, 2009, 5(6): 8-12. DOI: 10.3969/j.issn.1673-2227.2009.06.002
    [8]HUANG Jiansheng, LU Weihua, ZOU Weili, WANG Yao. Determination of residual polychlorinated biphenyls (PCBs) in blubber of whale by gel permeation chromatography and gas chromatography/mass spectrometry[J]. South China Fisheries Science, 2009, 5(4): 9-12. DOI: 10.3969/j.issn.1673-2227.2009.04.002
    [9]ZHANG Haiqi, HE Zhongyang, ZHENG Chongying, YE Leihai, SHI Like. High-performance liquid chromatography-tandem mass spectrometry for the determination of residue of malachite green in fishery products[J]. South China Fisheries Science, 2007, 3(6): 14-21.
    [10]XIE Yan, ZHANG Chaohua, LIU Shucheng, JI Hongwu, HONG Pengzhi. Analysis of fat content and fatty acid composition of eight trash fish in South China Sea[J]. South China Fisheries Science, 2007, 3(3): 47-52.

Catalog

    Article views PDF downloads Cited by()
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return