Citation: | PENG Yuanhuai, WANG Sheng, LI Chengpeng, CHEN Bitao, HUANG Yingli. Recycling of waste hydrochloric acid during chitin production process from Litopenaeus vannamei processing leftover[J]. South China Fisheries Science, 2017, 13(1): 104-109. DOI: 10.3969/j.issn.2095-0780.2017.01.013 |
To decrease environment pollution and reduce the cost of in production of chitin, the waste hydrochloric acid in the process of chitin production was studied, and the process conditions were optimized by single factor test and orthogonal test, using the reaction of sulfuric acid and calcium chloride to recover and recycle hydrochloric acid solution. The best regeneration parameters were obtained:room temperature, concentration of the sulfuric acid of 98%, the molar ratio of sulfate radical and calcium ion of 2.3 : 1, reaction time of 13 min, standing time of 3.5 h. Under these conditions, the regeneration rate was 91.51%, and the hydrochloric acid could be recycled five times and the calcium carbonate residues of the shrimp shell were no less than ≤1.2%.
[1] |
HONG K N, MEYERS S P, LEE K S.Isolation and characterization of chitin from crawfish shell waste[J].J Agric Food Chem, 1989, 37(3):575-579. doi: 10.1021/jf00087a001
|
[2] |
刘汉文, 王爱民, 陈洪兴, 等.甲壳素生产废水提取虾青素及水解蛋白的工艺研究[J].饲料工业, 2011, 32(14):51-55. doi: 10.3969/j.issn.1001-991X.2011.14.013
|
[3] |
吉惠杰, 马艳丽.蚕蛹甲壳素提取工艺研究[J].吉林化工学院学报, 2012, 29(5):28-33. http://www.cqvip.com/QK/96655X/201205/42293492.html
|
[4] |
蔚鑫鑫, 刘艳, 吴光旭.小龙虾壳中甲壳素的提取及壳聚糖的制备[J].湖北农业科学, 2013, 52(13):3120-3123. doi: 10.3969/j.issn.0439-8114.2013.13.041
|
[5] |
孙茜, 夏琪, 叶颖, 等.南美白对虾干虾壳甲壳素提取工艺比较及蛋白质回收[J].湖北农业科学, 2015, 54(15):3731-3734. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=hbny201515041&dbname=CJFD&dbcode=CJFQ
|
[6] |
张建英, 贾龙, 杨贵军, 等.黑皱鳃金龟甲壳素提取工艺研究[J].环境昆虫学报, 2015, 37(4):818-826. http://www.cqvip.com/QK/94519A/201504
|
[7] |
岁姗姗, 周祥, 周楷.正交试验法优化黄粉虫甲壳素提取新工艺[J].海南大学学报(自然科学版), 2015, 33(2):147-151. http://d.wanfangdata.com.cn/Periodical/hainandxxb201502011
|
[8] |
李婷, 程燕霞, 陈健聪, 等.利用有机酸结合蛋白酶从虾头虾壳中提取甲壳素[J].农产品加工(学刊), 2014(3):1-4, 7. http://www.cnki.com.cn/Article/CJFDTOTAL-NCJX201403002.htm
|
[9] |
窦勇, 胡佩红, 顾鹏程.超声波辅助EDTA法提取淡水小龙虾壳中甲壳素的工艺研究[J].广东农业科学, 2014, 41(22):87-91. doi: 10.3969/j.issn.1004-874X.2014.22.019
|
[10] |
窦勇, 胡佩红, 王芳.淡水小龙虾头中甲壳素的EDTA法提取工艺研究[J].农业科技与装备, 2014(3):59-61, 63. http://www.cqvip.com/QK/93806X/201422/663426778.html
|
[11] |
陈亚.提取甲壳素的乳酸菌发酵工艺优化[J].湖北农业科学, 2012, 51(20):4607-4609. doi: 10.3969/j.issn.0439-8114.2012.20.046
|
[12] |
黄璠, 张为巍, 周铭锋, 等.鼠李糖乳杆菌CLRI发酵虾壳脱钙的条件及培养基优化[J].贵州农业科学, 2011, 39(9):190-193. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=gate201109053&dbname=CJFD&dbcode=CJFQ
|
[13] |
李婷, 胡小喜, 周幸芝, 等.从虾蟹壳中提取甲壳素的研究进展[J].食品工业, 2014, 35(6):209-212. http://www.cqvip.com/QK/93886X/201406/49934716.html
|
[14] |
项东升, 李红梅.地产龙虾壳提取甲壳素及其废水的综合利用[J].食品与生物技术学报, 2008, 27(2):52-54. http://www.wenkuxiazai.com/doc/4fcf50b265ce0508763213be-2.html
|
[15] |
周湘池, 刘必谦, 徐君义, 等.甲壳质清洁生产中酸浸废液的处理与综合污水达标排放[J].宁波大学学报(理工版), 2006, 19(1):122-126. http://www.cqvip.com/qk/91297X/200601/21667216.html
|
[16] |
郑洪昌, 车均.氯离子浓度对污泥活性的影响及改善对策[J].山东理工大学学报(自然科学版), 2008, 22(1):103-106. http://www.docin.com/p-711343069.html
|
[17] |
黄明杰, 张杰.硫酸钙在花生种植中的应用综述[J].南方农业, 2015, 34(9):35-38. http://d.wanfangdata.com.cn/Periodical_nfny201534014.aspx
|
[18] |
扎西当知.浅谈饲料中钙源的种类及营养作用[J].甘肃畜牧兽医, 2015, 45(4):71-72. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=gxms201504051&dbname=CJFD&dbcode=CJFQ
|
[19] |
刘杰, 张杰.硫酸钙(石膏)在饲料矿物质钙中的应用现状及优势[J].饲料博览, 2015(12):31-34. doi: 10.3969/j.issn.1001-0084.2015.12.009
|
[20] |
黄筱萍, 张小华, 黄国昌.利用工业副产物硫酸钙制备建筑石膏的工艺研究[J].中国非金属矿工业导刊, 2014(2):20-22. http://www.doc88.com/p-6106678511818.html
|
[21] |
周晓东, 姚传捷, 邓晓清, 等.以脱硫石膏制备α型半水石膏晶须的研究[J].武汉工程大学学报, 2010, 32(11):62-64. http://www.cqvip.com/QK/90879A/201011/36004308.html
|
[22] |
邓志银, 袁义义, 孙骏, 等.pH值对脱硫石膏晶须生长行为的影响[J].过程工程学报, 2009, 9(6):1142-1146. http://www.cqvip.com/qk/94710A/200906/32502198.html
|
[23] |
黄俊娴, 杨建男.返滴定法监测EDTA处理虾壳制备甲壳素过程中的脱钙率[J].化学分析计量, 2007, 16(6):49-51. http://d.wanfangdata.com.cn/Periodical/hxfxjl200706017
|
[24] |
童华, 姚松年.蟹、虾壳微观形貌与结构研究[J].分析科学学报, 1997, 13(3):31-34. http://www.docin.com/p-744368837.html
|
[25] |
IFUKU S, NOGI M, ABE K, et al.Simple preparation method of chitin nanofibers with a uniform width of 10-20 nm from prawn shell under neutral conditions[J].Carbohydr Polym, 2011, 84(2, SI):762-764. doi: 10.1016/j.carbpol.2010.04.039
|
[26] |
陈魁, 向兰.硫酸钙溶解行为初探[J].盐业与化工, 2007, 36(2):1-3. http://www.cqvip.com/QK/92939A/2007002/24090746.html
|
[1] | LI Junwei, HU Ruiping, CHEN Suwen, GUO Yongjian, ZHU Changbo, LI Ting, XIE Xiaoyong, SU Jiaqi. Effects of low salinity pressure on biological tissue and immunity enzymes activities of Sipunculus nudus[J]. South China Fisheries Science, 2021, 17(4): 41-48. DOI: 10.12131/20210022 |
[2] | GE Wanyi, LEI Lina, JIANG Xinyu, LI Xia, SUN Zhaosheng, WANG Wei, GAO Qian. cDNA cloning and expression pattern analysis of b2m from spotted sea bass (Lateolabrax maculatus)[J]. South China Fisheries Science, 2020, 16(6): 47-56. DOI: 10.12131/20200031 |
[3] | YU Jiaxin, WU Fang, SUN Chengfei, DONG Junjian, TIAN Yuanyuan, YE Xing. Cloning, structure analysis and expression of interferon gamma (IFN-γ) gene in Oreochromis niloticus[J]. South China Fisheries Science, 2017, 13(1): 85-93. DOI: 10.3969/j.issn.2095-0780.2017.01.011 |
[4] | LIANG Nan, HU Kun, LIU Tengfei, WU Yingjie, YANG Xianle. Tissue distribution and elimination of methylene blue and its metabolites in allogynogenetic crucian carps (Carassius auratus gibelio)[J]. South China Fisheries Science, 2017, 13(1): 19-25. DOI: 10.3969/j.issn.2095-0780.2017.01.003 |
[5] | QIU Ying, HUANG Guiju, LIU Baosuo, FAN Sigang, LI Youning, CHEN Mingqiang, YU Dahui. Cloning of GLUT1 gene from winged pearl oyster Pteria penguin and its expression in response to glucose challenge[J]. South China Fisheries Science, 2016, 12(5): 81-89. DOI: 10.3969/j.issn.2095-0780.2016.05.010 |
[6] | LI Yundong, ZHOU Falin, HUANG Jianhua, MA Zhenhua, YANG Qibin, QIU Lihua, FU Mingjun, CHEN Jinsong, JIANG Shigui. Cloning and expression analysis of Cathepsin L cDNA of Penaeus monodon[J]. South China Fisheries Science, 2016, 12(3): 58-66. DOI: 10.3969/j.issn.2095-0780.2016.03.008 |
[7] | LIU Yujiao, ZHU Huaping, LU Maixin, LIU Zhigang, CAO Jianmeng, GAO Fengying, KE Xiaoli. Effect of salinity stress on expression of PRLⅠgenes from tilapia and their distribution in different tissues[J]. South China Fisheries Science, 2014, 10(6): 51-57. DOI: 10.3969/j.issn.2095-0780.2014.06.007 |
[8] | LI Wuhu, REN Chunhua, HU Chaoqun, JIANG Xiao, ZHONG Ming. cDNA cloning and tissue distribution of calmodulin from sea cucumber (Stichopus monotuberculatus)[J]. South China Fisheries Science, 2014, 10(5): 75-81. DOI: 10.3969/j.issn.2095-0780.2014.05.011 |
[9] | ZHANG Han, JIANG Jingzhe, HE Jian, GU Lu, WANG Jiangyong. Study on distribution of hemocyanin in different tissues of Haliotis diversicolor[J]. South China Fisheries Science, 2014, 10(4): 34-38. DOI: 10.3969/j.issn.2095-0780.2014.04.006 |
[10] | PAN Liling, HUANG Guiju, CHENG Shuying, WANG Xiaoning, YU Dahui. cDNA cloning, characterization and challenge-based expression profiles of cathepsin D in winged pearl oyster Pteria penguin[J]. South China Fisheries Science, 2012, 8(2): 22-29. DOI: 10.3969/j.issn.2095-0780.2012.02.004 |