WANG Lunan, YANG Shaoling, QI Bo, YANG Xianqing, LI Chunsheng, MA Haixia, HU Xiao. Effect of three modification methods on physicochemical properties of agar[J]. South China Fisheries Science, 2021, 17(2): 97-103. DOI: 10.12131/20200197
Citation: WANG Lunan, YANG Shaoling, QI Bo, YANG Xianqing, LI Chunsheng, MA Haixia, HU Xiao. Effect of three modification methods on physicochemical properties of agar[J]. South China Fisheries Science, 2021, 17(2): 97-103. DOI: 10.12131/20200197

Effect of three modification methods on physicochemical properties of agar

More Information
  • Received Date: September 21, 2020
  • Revised Date: November 18, 2020
  • Available Online: December 11, 2020
  • In this study, agar was modified by carboxymethylation, hydrogen peroxide oxidation and hydroxypropylation to compare the solubility, color, gel transparency, gel texture, IR molecular structure and thermal stability before and after the modification, aiming to explore the influence of three modification treatments on the physicochemical properties of agar. The results show that the dissolving temperature, gelling temperature, melting temperature and gel strength decreased significantly after carboxymethylation and hydroxypropyl treatments (P<0.05), whereas the soft elasticity and water holding capacity of agar gel improved; the gel strength of agar was improved by oxidation treatment (P<0.05), from 984 g·cm−2 to 1 463 g·cm−2; after oxidation and hydroxypropylation, the modified agar showed higher whiteness (P<0.05), while carboxymethyl agar was on the contrary (P<0.05). Besides, all modifications had increased the transparency of agar gel significantly (P<0.05). The thermal stability increased with oxidation and hydroxypropylation, but reduced with carboxymethylation. In conclusion, three modification methods can improve physicochemical properties of agar at different extents.
  • [1]
    林坤城. 琼脂提取及深加工研究进展[J]. 福建农业科技, 2018(9): 60-64.
    [2]
    WANG L J, SHEN Z P, MU H M, et al. Impact of alkali pretreatment on yield, physico-chemical and gelling properties of high quality agar from Gracilaria tenuistipitata[J]. Food Hydrocolloid, 2017, 70: 356-362. doi: 10.1016/j.foodhyd.2016.11.042
    [3]
    马军, 侯萍, 陈燕, 等. 几种海藻多糖抗氧化活性及体外抗脂质过氧化作用的研究[J]. 南方水产科学, 2017, 13(6): 97-104. doi: 10.3969/j.issn.2095-0780.2017.06.012
    [4]
    孙利军, 夏和咏, 罗枭, 等. 琴岛寒天物化特性、生产工艺及其在食品中的应用[C]//第十五届中国国际食品添加剂和配料展览会学术论文集. 北京: 《中国食品添加剂》杂志社, 2011: 5.
    [5]
    嵇海峰, 肖安风. 一种高透明度高凝胶强度改性琼脂的制备方法: 201910330126.8[P]. 2019-07-12.
    [6]
    薛玉玲, 杨瑞, 朱宏, 等. 几种海洋多糖在搅拌型酸乳中增稠特性比较研究[J]. 乳业科学与技术, 2016, 39(2): 8-10.
    [7]
    问莉莉. 高品质琼胶的制备及其稳定性研究[D]. 湛江: 广东海洋大学, 2013: 3-9.
    [8]
    XIA K, LIU X, ZHAO J K, et al. The physicochemical property characterization of agar acetate[J]. Carbohydr Polym, 2014, 110: 32-37. doi: 10.1016/j.carbpol.2014.03.036
    [9]
    KAMALESH P, KEYUR T, RAMAVATAR M, et al. Physical modification of agar: formation of agar-fatty acid complexes[J]. Polym J, 2005, 37: 826-832. doi: 10.1295/polymj.37.826
    [10]
    HAQ F, YU H J, WANG L, et al. Advances in chemical modifications of starches and their applications[J]. Carbohydr Res, 2019, 476: 12-35. doi: 10.1016/j.carres.2019.02.007
    [11]
    王丹, 王宝庆, 廖耀华, 等. 琼脂及其降解产物的应用和低温溶解琼脂的制备进展[J]. 中外食品工业, 2015, 93(3): 93-95.
    [12]
    别蒙, 谢笔钧, 孙智达. 不同取代度水溶性羧甲基茯苓多糖的制备、结构表征及体外抑菌活性[J]. 食品科学, 2020, 41(12): 67-76.
    [13]
    XIAO Q, AN D, ZHANG C, et al. Agar quality promotion prepared by desulfation with hydrogen peroxide[J]. Int J Biol Macromol, 2019, 145: 492-499.
    [14]
    ZHANG X D, LIU X, CAO M Z, et al. Preparation of hydroxypropyl agars and their properties[J]. Carbohydr Polym, 2015, 129: 87-91. doi: 10.1016/j.carbpol.2015.04.056
    [15]
    XIAO Q, WENG H F, NI H, et al. Physicochemical and gel properties of agar extracted by enzyme and enzyme-assisted methods[J]. Food Hydrocolloid, 2018, 87: 260-305.
    [16]
    GOPE S, SAMYOR D, PAUL A K, et al. Effect of alcohol-acid modification on physicochemical, rheological and morphological properties of glutinous rice starch[J]. Int J Biol Macromol, 2016, 93(Pt A): 860-867.
    [17]
    杜建华, 李婷, 倪辉, 等. 以江蓠琼脂为原料制备生化琼脂[J]. 过程工程学报, 2018, 3(2): 434-440.
    [18]
    顾熟琴, 段慧玲, 赵镭, 等. 建立食品质地参照物体系中量值估计法的改进[J]. 中国粮油学报, 2014, 29(1): 95-100.
    [19]
    李晓艺, 苏现波, 韩霜, 等. 大目金枪鱼皮明胶与κ-卡拉胶复配胶凝胶特性探究[J]. 食品工业科技, 2018, 39(19): 13-19.
    [20]
    CAO M Z, LIU X, LUAN J M, et al. Characterization of physicochemical properties of carboxymethyl agar[J]. Carbohydr Polym, 2014, 111: 449-455. doi: 10.1016/j.carbpol.2014.04.036
    [21]
    戚勃, 李来好, 杨贤庆, 等. 响应曲面法优化麒麟菜卡拉胶碱处理工艺[J]. 南方水产科学, 2011, 7(6): 26-34.
    [22]
    李琴梅, 戚勃. 琼脂的物化特性及其在食品工业中的应用[J]. 中国食品添加剂, 2009, 20(6): 148-152.
    [23]
    ZHANG C, AN D, XIAO Q, et al. Preparation, characterization, and modification mechanism of agar treated with hydrogen peroxide at different temperatures[J]. Food Hydrocolloid, 2020, 101: 105527. doi: 10.1016/j.foodhyd.2019.105527
    [24]
    WANG L F, PAN S Y, HU H, et al. Synthesis and properties of carboxymethyl kudzu root starch[J]. Carbohydr Polym, 2010, 80(1): 174-179. doi: 10.1016/j.carbpol.2009.11.008
    [25]
    PABLO M P, MARIA C P, PABLO D R. Impact of chemical modifications in pilot-scale isolated sorghum starch and commercial cassava starch[J]. Int J Biol Macromol, 2019, 135: 521-529. doi: 10.1016/j.ijbiomac.2019.05.202
    [26]
    马云, 杨玉玲, 杨震, 等. 琼脂凝胶质构特性的研究[J]. 食品与发酵工业, 2007, 237(9): 24-27.
    [27]
    CASTANHA N, JUNIOR M D D M, AUGUSTO P E D. Potato starch modification using the ozone technology[J]. Food Hydrocolloid, 2017, 66: 343-356. doi: 10.1016/j.foodhyd.2016.12.001
    [28]
    赵巧娇. 羧甲基板栗淀粉的制备及性质研究[D]. 北京: 北京林业大学, 2016: 19-35.
    [29]
    黄海潮, 王锦旭, 潘创, 等. 超声波辅助过氧化氢法降解坛紫菜多糖及其抗氧化活性的研究[J]. 南方水产科学, 2020, 16(1): 110-119.
    [30]
    李龙. 龙须菜琼脂糖的提取技术研究[D]. 福州: 福建农林大学, 2013: 26-34.
    [31]
    LAWAL O S, LECHNER M D, KULICKE W M. Single and multi-step carboxymethylation of water yam (Dioscorea alata) starch: synthesis and characterization[J]. Int J Biol Macromol, 2008, 46(5): 429-435.
    [32]
    钟振声, 钟艳萍, 孙昂. 马铃薯交联羧甲基淀粉的结构与性能[J]. 华南理工大学学报(自然科学版), 2011, 39(3): 22-27.
    [33]
    SAKSHI S, SUKHCHARN S, CHARANJIT S R. Effect of oxidation, cross-linking and dual modification on physicochemical, crystallinity, morphological, pasting and thermal characteristics of elephant foot yam (Amorphophallus paeoniifolius) starch[J]. Food Hydrocolloid, 2016, 55: 56-64. doi: 10.1016/j.foodhyd.2015.11.003
    [34]
    ZHANG Y R, WANG X L, ZHAO G M, et al. Preparation and properties of oxidized starch with high degree of oxidation[J]. Carbohydr Polym, 2012, 87(4): 2554-2562. doi: 10.1016/j.carbpol.2011.11.036
  • Related Articles

    [1]DONG Mei, FENG Kecheng, SHEN Ziyi, HUANG Ju. Study on preparation of Sargassum fusiforme oligosaccharides by enzyme and its antioxidant and antibacterial properties[J]. South China Fisheries Science, 2025, 21(2): 191-200. DOI: 10.12131/20240244
    [2]LU Chen, HU Xiao, CHEN Shengjun, WU Yanyan, HUANG Hui, XIANG Huan, QI Bo, DENG Jianchao. Preparation, in vitro activity and physicochemical properties of collagenase inhibitory peptide from tilapia skin[J]. South China Fisheries Science, 2024, 20(2): 150-159. DOI: 10.12131/20230205
    [3]LENG Meng, LIN Duanquan, WENG Ling, ZHANG Lingjing, MIAO Song, CAO Minjie, SUN Lechang. Enzymatic extraction and physicochemical properties of Porphyra haitanensis protein[J]. South China Fisheries Science, 2023, 19(3): 140-150. DOI: 10.12131/20220242
    [4]HUO Yumei, HU Xiao, WU Yanyan, JIANG Jinjin. Preparation, separation and physicochemical properties of α-glucosidase inhibitory peptides from Miichthys miiuy[J]. South China Fisheries Science, 2023, 19(3): 98-109. DOI: 10.12131/20220269
    [5]QI Bo, YANG Shaoling, WANG Yueqi, HU Xiao, YANG Xianqing, PAN Chuang, LI Laihao, WANG Lunan. Effect of carboxymethyl agar on gel properties of tilapia surimi[J]. South China Fisheries Science, 2022, 18(2): 83-89. DOI: 10.12131/20210311
    [6]HUANG Haichao, WANG Jinxu, PAN Chuang, YANG Xianqing, QI Bo, LI Laihao, ZHAO Yongqiang. Degradation of Porphyra haitanensis polysaccharide by ultrasonic assisted hydrogen peroxide method and its antioxidant activity analysis[J]. South China Fisheries Science, 2020, 16(1): 110-119. DOI: 10.12131/20190220
    [7]QIU Chaoying, RONG Jing, HU Xiao, YANG Xianqing, LI Laihao, HUANG Hui. Antioxidant properties of simulated in vitro digests of glycosylated Symplectoteuthis oualaniensis myofibrillar protein[J]. South China Fisheries Science, 2018, 14(6): 105-112. DOI: 10.12131/20180074
    [8]LI Laihao, YE Ge, HAO Shuxian, WEI Ya, HUANG Hui, LIN Wanling, CEN Jianwei. Comparison on quality of tilapia under two kinds of culture modes[J]. South China Fisheries Science, 2013, 9(5): 1-6. DOI: 10.3969/j.issn.2095-0780.2013.05.001
    [9]ZENG Shaokui, LIU Kun, WU Yitang, WU Wenlong, YIN Juanjuan, SHI Wen. Extraction optimization and physicochemical properties of gelatin from demineralized scale of Oreochromis nilotica[J]. South China Fisheries Science, 2013, 9(2): 38-44. DOI: 10.3969/j.issn.2095-0780.2013.02.007
    [10]PENG Wen, JIANG Jing-zhe, WANG Jiang-yong, DING Xue-juan. Effect of physicochemical factors on phenoloxidase activity of hemocyanin from abalone Haliotis diversicolor[J]. South China Fisheries Science, 2010, 6(2): 1-6. DOI: 10.3969/j.issn.1673-2227.2010.02.001
  • Cited by

    Periodical cited type(21)

    1. 黄宏,刘怡琳,俞锦辰,兰艳,赵旭,王钻一,李迎东,储鸣. 马袅湾网箱养殖对沉积物营养盐的影响. 海洋湖沼通报. 2024(03): 129-140 .
    2. 姚德强,孙伟杰,孙博怿,徐卫国,沈天富,吕烨锋,王珏,施沁璇. 桐乡市渔业水环境时空变化及其影响因素. 浙江农业科学. 2024(07): 1720-1726 .
    3. 薛尊,石建高,张文阳. 中国重力式深水网箱研究进展和展望. 渔业研究. 2024(04): 393-402 .
    4. 陈军,胡高宇,陈飞,蔡逸龙,陈然,沈海钰,李敏. 温岭隘顽湾海水养殖区池塘水质状况调查与评价. 浙江海洋大学学报(自然科学版). 2024(03): 260-267 .
    5. 庞巧珠,陈丹丹,陈晓慧,谢海群,梁计林. 后水湾深水网箱养殖区水环境的时空变化和营养状态分析. 广西科学. 2024(04): 742-753 .
    6. 刘雁,佟飞,陈丕茂,袁华荣,冯雪. 海水养殖尾水总磷测定方法的比较与优化. 南方水产科学. 2023(01): 58-66 . 本站查看
    7. 葛伟宏,王兴强,苏家齐,朱长波. 大亚湾深水网箱养殖海域表层沉积物碳、氮、磷分布特征及污染评估. 江苏海洋大学学报(自然科学版). 2023(04): 51-59 .
    8. 王枫林,高云涛,高云红,李明月,张秉智,关长涛,贾玉东. 斑石鲷陆海接力养殖初步研究. 渔业现代化. 2022(04): 8-14 .
    9. 苏家齐,朱长波,张博,陈素文,李婷. 海陵湾网箱养殖区浮游植物群落结构及其与环境因子的关系. 上海海洋大学学报. 2022(04): 929-939 .
    10. 陈丹丹,庞巧珠,涂志刚,谢海群,陈晓慧. 后水湾深水网箱养殖区浮游植物群落季节变化及其与环境因子的关系. 海洋环境科学. 2021(01): 73-80 .
    11. 阮素玲,李敏,陆荣茂,肖国强,张翔,陆振. 南麂海域水质营养盐和表层沉积物重金属污染评价. 安徽农业科学. 2021(12): 60-63 .
    12. 段丁毓,秦传新,朱文涛,马鸿梅. 海洋牧场景观生态分类研究:以柘林湾海洋牧场为例. 渔业科学进展. 2020(02): 1-11 .
    13. 杨文超,黄道建,陈继鑫,陈晓燕,王宇珊,孙丽梅. 大亚湾2010—2018年表层沉积物中重金属含量时空分布及生态风险评价. 南方水产科学. 2020(04): 39-46 . 本站查看
    14. 杨文超,黄道建,陈继鑫,陈晓燕,王宇珊,孙丽梅. 大亚湾海域2009—2018年重金属时空分布及污染评价. 华南师范大学学报(自然科学版). 2020(05): 65-75 .
    15. 陈丹丹,庞巧珠,陈晓慧,孙婆援,涂志刚. 2018年春秋季海南后水湾浮游植物群落结构特征及其与环境因子的关系. 海洋湖沼通报. 2020(05): 113-120 .
    16. 杨文超,黄道建,陈继鑫,陈晓燕,王宇珊. 大亚湾近十年沉积物中汞、砷分布及污染评价. 水产科学. 2020(06): 915-921 .
    17. 石一茜,赵旭,林军,李大鹏,黄宏,章守宇. 基于总量和形态的表层沉积物重金属污染及来源——以马鞍列岛海域为例. 中国环境科学. 2019(03): 1189-1198 .
    18. 席小慧,尤广然,吴英超,刘明,赵东洋. 庄河市海洋牧场发展需求及布局策略研究. 渔业研究. 2019(03): 252-257 .
    19. 陈得仿,王腾,刘永,肖雅元,王九江,李纯厚. 大亚湾黑鲷繁殖特征的生物学研究. 南方水产科学. 2019(05): 41-47 . 本站查看
    20. 王毛兰,刘景景. 鄱阳湖网箱养殖对水环境的影响——以都昌水域为例. 环境化学. 2019(10): 2348-2355 .
    21. 雷建军,王大鹏,肖俊军,何安尤,李育森. 广西岩滩水库不同养殖类型区域沉积物磷分布特征分析. 南方农业学报. 2017(12): 2288-2294 .

    Other cited types(14)

Catalog

    Article views (1257) PDF downloads (74) Cited by(35)
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return