东莞及其邻近海域经济鱼类体内滴滴涕残留特征及风险评价

Residues and risk assessment of dichlorodiphenyl trichloroethanes in commercial fishes from Dongguan and its adjacent waters

  • 摘要: 采用Agilent 7890N型气相色谱仪、毛细管色谱柱(HP-5 30 m×320 μm×0.25 μm)和ECD检测器测定了东莞及其邻近海域6种经济鱼类体内的滴滴涕(DDTs)残留量。结果显示, 鱼类体内残留的w(DDTs)为1.527~24.842 μg·kg-1, 最高的为凤鲚(Coilia mystus), 其后为尖尾鳗(Uroconger lepturus)和龙头鱼(Harpadon nehereus); 鱼类体内DDTs的4种同分异构体中, w(P, P'-DDE)最高, 其后为w(P, P'-DDD)、w(P, P'-DDT)和w(O, P'-DDT), 其所占总量百分比的平均值分别为44.55%、29.19%、22.01%和4.25%;东莞及其邻近海域内应无新的DDTs污染源输入, 鱼体内的DDTs可能来自过去的污染, 对人体健康不构成威胁。

     

    Abstract: We determined the residues of dichlorodiphenyl trichloroethanes (DDTs) in 6 species of commercial fishes from Dongguan and its adjacent waters by Agilent 7890N GC, capillary column (HP-5 30 m×250 μm×0.25 μm) and ECD detector. Results show that the DDTs residues in those fishes are 1.527~24.842 μg·kg-1. Coilia mystus has the highest content of DDTs residues, followed by Uroconger lepturus and Harpadon nehereus. The average content of P, P'-DDE, P, P'-DDD, P, P'-DDT and O, P'-DDT is 44.55%, 29.19%, 22.01% and 4.25%, respectively. Since no new pollution source of DDTs was found, the DDTs in those fishes might come from the past pollution and pose no significant threat to human health.

     

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